Interplay between magnetic, electronic, and vibrational effects in monolayer Mn3O4 grown on Pd(100)

Author(s)
Cesare Franchini, Jan Zabloudil, Raimund Podloucky, Francesco Allegretti, Fanghua Li, Svetlozar L. Surnev, Falko P. Netzer
Abstract

The surface stabilized MnO(100)-like monolayer, characterized by a regular c (4×2) distribution of Mn vacancies, is studied by hybrid functionals and discussed in the light of available scanning tunneling microscopy and high-resolution electron energy loss spectroscopy data. We show that the use of hybrid functionals is crucial to account for the intermingled nature of magnetic interactions, electron localization, structural distortions, and surface phonons. The proposed Pd(100) supported Mn3O4 structure is excellently compatible with the experiments previously reported in literature.

Organisation(s)
Computational Materials Physics, Department of Physical Chemistry
External organisation(s)
Karl-Franzens-Universität Graz
Journal
Journal of Chemical Physics
Volume
130
No. of pages
6
ISSN
0021-9606
DOI
https://doi.org/10.1063/1.3097957
Publication date
2009
Peer reviewed
Yes
Austrian Fields of Science 2012
104017 Physical chemistry, 104011 Materials chemistry, 103018 Materials physics
Portal url
https://ucrisportal.univie.ac.at/en/publications/interplay-between-magnetic-electronic-and-vibrational-effects-in-monolayer-mn3o4-grown-on-pd100(1b531944-8f41-4aa7-8425-d932749aa3b2).html