Vacancy walk and its impact on the character of phase transitions

Author(s)
David Reith, Wolfgang Püschl, Wolfgang Pfeiler, Ferdinand Haider
Abstract

The vacancy walk in intermetallics of type L12 and B2 was studied by using Monte-Carlo simulation with a residence time algorithm. To decide between a homogeneous or heterogeneous state of the system, a coarse graining procedure was introduced, and the mean square deviation of the local order parameter was taken as a measure of heterogeneity. It was found that a sufficient fraction of lattice sites must be visited by a vacancy so that a phase transformation can be observed as homogeneous throughout the volume of a crystal. It is explained why this criterion should be preferred over an earlier one where overlap of the mean quadratic random walk distances of vacancy migration was considered.

Organisation(s)
Computational Materials Physics
External organisation(s)
Universität Augsburg
Volume
2
Pages
765-770
No. of pages
6
Publication date
2005
Austrian Fields of Science 2012
1030 Physics, Astronomy
Portal url
https://ucrisportal.univie.ac.at/en/publications/vacancy-walk-and-its-impact-on-the-character-of-phase-transitions(1fe460cf-0b4a-495b-92ef-7c288aa61f52).html