Oxygen-Stabilized Rh Adatoms: 0D Oxides on a Vicinal Surface

Author(s)
Florian Mittendorfer, Thomas Franz, J Klikovits, Michael Schmid, Lindsay R. Merte, Sameena Shah Zaman, Peter Varga, Rasmus Westerström, Andrea Resta, Jesper N. Andersen, Johan Gustafson, Edvin Lundgren
Abstract

We have investigated the initial oxidation of the Rh(113) and Rh(223) vicinal surfaces by STM and ab initio simulations. Upon adsorption of small amounts of oxygen, the surface morphology is completely altered. Surprisingly, oxygen-stabilized Rh adatoms can be observed on the (113) facets, with oxide-like electronic properties. We present models of these "0D oxide" phases and discuss reasons for their stability.

Organisation(s)
Computational Materials Physics
External organisation(s)
Technische Universität Wien, Lund University
Journal
The Journal of Physical Chemistry Letters
Volume
2
Pages
2747-2751
No. of pages
5
DOI
https://doi.org/10.1021/jz2011308
Publication date
2011
Peer reviewed
Yes
Austrian Fields of Science 2012
103018 Materials physics
Portal url
https://ucris.univie.ac.at/portal/en/publications/oxygenstabilized-rh-adatoms-0d-oxides-on-a-vicinal-surface(b5483235-5013-45f8-9029-50e088f1d870).html