Theory of Spin-Conserving Excitation of the N-V Center in Diamond

Author(s)
Adam Gali, Erik Janzen, Péter Deák, Georg Kresse, Efthimios Kaxiras
Abstract

The negatively charged nitrogen-vacancy defect in diamond is an important atomic-scale structure that can be used as a qubit in quantum computing and as a marker in biomedical applications. Its usefulness relies on the ability to optically excite electrons between well-defined gap states, which requires a clear and detailed understanding of the relevant states and excitation processes. Here we show that by using hybrid density-functional-theory calculations in a large supercell we can reproduce the zero-phonon line and the Stokes and anti-Stokes shifts, yielding a complete picture of the spin-conserving excitation of this defect.

Organisation(s)
Computational Materials Physics
External organisation(s)
Budapest University of Technology and Economics, Linköping University, Universität Bremen, Harvard University
Journal
Physical Review Letters
Volume
103
No. of pages
4
ISSN
0031-9007
DOI
https://doi.org/10.1103/PhysRevLett.103.186404
Publication date
2009
Peer reviewed
Yes
Austrian Fields of Science 2012
1030 Physics, Astronomy
Portal url
https://ucrisportal.univie.ac.at/en/publications/db314bf2-7dd3-47c8-a975-b29cd9224683